"The Messenger of Allah ﷺ used to pray Zuhr when the sun passed its zenith, and he would pray 'Asr between these two prayers; and he would pray Maghrib when the sun had set, and he used to pray 'Isha' when the twilight had disappeared," then he said straight after that: "And he would pray Fajr when a man could see clearly." (Using translation from Nasāʾī 552)
عَنْ صَلَاةِ رَسُولِ اللهِ ﷺ فَقَالَ كَانَ يُصَلِّي الظُّهْرَ إِذَا زَالَتِ الشَّمْسُ وَالْعَصْرَ بَيْنَ صَلَاتَيْكُمْ هَاتَيْنِ وَالْمَغْرِبَ إِذَا غَرَبَتِ الشَّمْسُ وَالْعِشَاءَ إِذَا غَابَ الشَّفَقُ وَالصُّبْحَ إِذَا طَلَعَ الْفَجْرُ إِلَى أَنْ يَنْفَسِحَ الْبَصَرُ