The Apostle ﷺ woke up at night; relieved himself, and then washed his face and hands and then again slept. (Using translation from Muslim 304)
أَنَّ رَسُولَ اللهِ ﷺ قَامَ مِنَ اللَّيْلِ فَقَضَى حَاجَتَهُ ثُمَّ غَسَلَ وَجْهَهُ وَيَدَيْهِ ثُمَّ جَاءَ فَنَامَ