I saw the Messenger of Allah ﷺ throwing pebbles on the day of sacrifice while on his riding beast in the forenoon, and next when the sun had passed the meridian. (Using translation from Abū Dāʾūd 1971)
سَمِعْتُ جَابِرَ بْنَ عَبْدِ اللهِ يَقُولُ رَأَيْتُ رَسُولَ اللهِ ﷺ يَرْمِي يَوْمَ النَّحْرِ ضُحًى وَحْدَهُ وَأَمَّا بَعْدَ ذَلِكَ فَبَعْدَ زَوَالِ الشَّمْسِ