Whenever the Prophet ﷺ used to offer prayer he used to keep arms away (from the body) so that the whiteness of his armpits was visible.  

أَنَّ النَّبِيَّ ﷺ كَانَ إِذَا صَلَّى فَرَّجَ بَيْنَ يَدَيْهِ حَتَّى يَبْدُوَ بَيَاضُ إِبْطَيْهِ وَقَالَ اللَّيْثُ حَدَّثَنِي جَعْفَرُ بْنُ رَبِيعَةَ نَحْوَهُ