Whenever the Prophet ﷺ started a journey before noon, he used to delay the Zuhr prayer till the time of ʿAsr and then offer them together; and if the sun declined (at noon) he used to offer the Zuhr prayer and then ride (for the journey). (Using translation from Bukhārī 1110)
أَنَّ رَسُولَ اللهِ ﷺ كَانَ يَجْمَعُ بَيْنَ هَاتَيْنِ الصَّلَاتَيْنِ فِي السَّفَرِ يَعْنِي الْمَغْرِبَ وَالْعِشَاءَ