Whenever the Prophet ﷺ started on a journey before noon, he used to delay the Zuhr prayers till the time for the 'Asr prayer and then he would dismount and offer them together; and whenever the sun declined before he started on a journey he used to offer the Zuhr prayers and then ride (for journey).  

كَانَ رَسُولُ اللَّهِ ﷺ إِذَا ارْتَحَلَ قَبْلَ أَنْ تَزِيغَ الشَّمْسُ أَخَّرَ الظُّهْرَ إِلَى وَقْتِ الْعَصْرِ ثُمَّ نَزَلَ فَجَمَعَ بَيْنَهُمَا فَإِنْ زَاغَتِ الشَّمْسُ قَبْلَ أَنْ يَرْتَحِلَ صَلَّى الظُّهْرَ ثُمَّ رَكِبَ