Caution: Translations of Quran and Ḥadīth may lead to possible misapplications and misinterpretations. This site is intended for students of sacred knowledge that are proficient in comprehending classical Arabic and have a strong foundation in Islamic sciences. Also note that religious injunctions rely on several aspects beyond what one may glean through reading individual aḥādīth.
ahmad:1242ʿAbdullāh > Abū ʿAbd al-Raḥman ʿAbdullāh b. ʿUmar > ʿAbd al-Raḥīm al-Rāzī > Zakariyyā b. Abū Zāʾidah And al-ʿAlāʾ b. al-Musayyab > Abū Isḥāq > ʿĀṣim b. Ḍamrah > Ataynā ʿAlī b. Abū Ṭālib Faqulnā Yā Amīr al-Muʾminīn Alā

We came to ʿAli bin Abi Talib ؓ and said: O Ameer al-Muʿmineen, why donʿt you tell us about the voluntary prayer of the Messenger of Allah ﷺ? He said: Who among you can do that? They said: We will take what we can do. He said: The Messenger of Allah ﷺ used to pray sixteen rakʿahs during the day apart from the Prescribed prayers.  

أحمد:١٢٤٢حَدَّثَنَا عَبْدُ اللهِ حَدَّثَنِي أَبُو عَبْدِ الرَّحْمَنِ عَبْدُ اللهِ بْنُ عُمَرَ أَخْبَرَنَا عَبْدُ الرَّحِيمِ الرَّازِيُّ عَنْ زَكَرِيَّا بْنِ أَبِي زَائِدَةَ وَالْعَلاءِ بْنِ الْمُسَيَّبِ عَنْ أَبِي إِسْحَاقَ عَنْ عَاصِمِ بْنِ ضَمْرَةَ قَالَ أَتَيْنَا عَلِيَّ بْنَ أَبِي طَالِبٍ فَقُلْنَا يَا أَمِيرَ الْمُؤْمِنِينَ أَلا

تُحَدِّثُنَا عَنْ صَلاةِ النَّبِيِّ ﷺ تَطَوُّعَهُ؟ فَقَالَ وَأَيُّكُمْ يُطِيقُهُ؟ قَالُوا نَأْخُذُ مِنْهُ مَا أَطَقْنَا قَالَ كَانَ رَسُولُ اللهِ ﷺ يُصَلِّي مِنَ النَّهَارِ سِتَّ عَشْرَةَ رَكْعَةً سِوَى الْمَكْتُوبَةِ